SYNTHESIS AND LIGATIVE BEHAVIOR OF A GALLACYCLOPENTADIENE Academic Article

abstract

• In a simple exchange reaction zirconacycle 1 is converted into the new heterocycles 2 and 3 by treatment with ArGaCl2 and ArInBr2, respectively. Gallacyclopentadiene 2 is monomeric and its fivemembered ring is planar. The cyclopentadiene ring and the aryl ring are nearly orthogonal owing to steric interactions. Compound 2 can be converted readily into a (C5H5)Co complex. Ar = 2,4,6tBu3C6H2. (Figure Presented.) Copyright 1994 by VCH Verlagsgesellschaft mbH, Germany

authors

• Gabbai, Francois

published proceedings

• ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

• COWLEY, A. H., GABBAI, F. P., & DECKEN, A.

citation count

• 30

complete list of authors

• COWLEY, AH||GABBAI, FP||DECKEN, A

publication date

• July 1994

publisher

• Wiley  Publisher

published in

• Angewandte Chemie - International Edition  Journal

Digital Object Identifier (DOI)

• 10.1002/anie.199413701

start page

• 1370

end page

• 1372

volume

• 33

issue

• 13

URL

• http://dx.doi.org/10.1002/anie.199413701