INTRAMOLECULAR BASE STABILIZATION OF COBALT-GALLIUM AND COBALT-INDIUM COMPOUNDS Academic Article uri icon

abstract

  • The intermetallic derivatives [{(2,6-Me2- NCH2)2C6H3}M{Co(CO)4}2] (M = Ga (1); M = In (2)) have been prepared. X-ray analysis reveals that only one of the dimethylamine groups is coordinated to Ga in 1 and as a consequence the CGaCo2 moiety is pyramidal; the indium analogue 2 possesses a distorted-trigonal-bipyramidal geometry and a planar CInCo2 unit. 1994, American Chemical Society. All rights reserved.

published proceedings

  • ORGANOMETALLICS

author list (cited authors)

  • OLAZABAL, C. A., GABBAI, F. P., COWLEY, A. H., CARRANO, C. J., MOKRY, L. M., & BOND, M. R.

citation count

  • 37

complete list of authors

  • OLAZABAL, CA||GABBAI, FP||COWLEY, AH||CARRANO, CJ||MOKRY, LM||BOND, MR

publication date

  • February 1994