INTRAMOLECULAR BASE STABILIZATION OF COBALT-GALLIUM AND COBALT-INDIUM COMPOUNDS
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The intermetallic derivatives [{(2,6-Me2- NCH2)2C6H3}M{Co(CO)4}2] (M = Ga (1); M = In (2)) have been prepared. X-ray analysis reveals that only one of the dimethylamine groups is coordinated to Ga in 1 and as a consequence the CGaCo2 moiety is pyramidal; the indium analogue 2 possesses a distorted-trigonal-bipyramidal geometry and a planar CInCo2 unit. 1994, American Chemical Society. All rights reserved.