REACTIVITY OF A PHOSPHANYLCARBENE (LAMBDA(5)-PHOSPHAACETYLENE) WITH LEWIS-ACIDS - X-RAY CRYSTAL-STRUCTURES OF THE FIRST CARBENE-GALLANE COMPLEX AND C-GALLYL-SUBSTITUTED PHOSPHORUS YLIDE Academic Article uri icon

abstract

  • A remarkably diverse reactivity toward Lewis acids is exhibited by the phosphanylcarbene (R2N)2PCSiMe3 (R cC6H11). The methylated Lewis acids MMe3 (M Al, Ga, In) undergo 1,2 addition reactions to form the Csubstituted phosphorylides 1 (X Me), while the corresponding chlorides MCl3 form the first stable phosphanylcarbeneLewis acid complexes 2 (X Cl). (Figure Presented.) Copyright 1994 by VCH Verlagsgesellschaft mbH, Germany

published proceedings

  • ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

  • COWLEY, A. H., GABBAI, F. P., CARRANO, C. J., MOKRY, L. M., BOND, M. R., & BERTRAND, G.

citation count

  • 33

complete list of authors

  • COWLEY, AH||GABBAI, FP||CARRANO, CJ||MOKRY, LM||BOND, MR||BERTRAND, G

publication date

  • March 1994

publisher