SURPRISING STABILITY OF A MONOMERIC BIS AZIDE OF GALLIUM(III) Academic Article

abstract

• The intramolecularly base-stabilized arylgallium diazide [2,6-(Me2NCH2)2C6H3]Ga(N3)2 (1) has been prepared by a metathetical reaction of the corresponding arylgallium dichloride with NaN3. Compound 1 was found not only to be air stable, but also to survive vapor phase heating at 400C or UV irradiation at 254 nm. The X-ray crystal structure of 1 has been determined; triclinic, P1, with a = 8.861(2), b = 10.445(4), c = 11.562(4) A , = 107.07(3), = 105. 92(2), = 101.35(3), V = 937.9(5) A 3 and Z = 2. Compound 1 is monomeric in the solid state. 1995.

authors

• Gabbai, Francois

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• COWLEY, A. H., GABBAI, F. P., OLBRICH, F., CORBELIN, S., & LAGOW, R. J.

citation count

• 25

complete list of authors

• COWLEY, AH||GABBAI, FP||OLBRICH, F||CORBELIN, S||LAGOW, RJ

publication date

• February 1995

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• Aryls
• Azides
• Gallium
• X-ray Crystal Structure

Digital Object Identifier (DOI)

• 10.1016/0022-328X(94)05131-T

start page

• C5

end page

• C7

volume

• 487

issue

• 1-2

URL

• http://dx.doi.org/10.1016/0022-328x(94)05131-t