STRUCTURAL INVESTIGATION INTO THE SURPRISING STABILITY OF FREE AND COMPLEXED BIS(AMINO)PHOSPHINE AZIDES

abstract

• The reaction of (iPr2N)2PN3 (1) with Fe2(CO)9 in toluene solution at 25C produces the complex (iPr2N)2P(N3)-Fe(CO)4 (3) with a high yield. The cophotolysis of 1 and Cr(CO)6 in tetrahydrofuran solution results in the formation of (iPr2N)2P(N3)-Cr(CO) 5 (4). Complexes 3 and 4 were found to be stable to UV irradiation (254 nm). The chromium complex 4 and the free phosphine azide (c-Hex2N)2PN3 (2) have been characterized by single-crystal X-ray diffraction. 1995.

authors

• Gabbai, Francois

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• COWLEY, A. H., GABBAI, F. P., BERTRAND, G., CARRANO, C. J., & BOND, M. R.

citation count

• 12

complete list of authors

• COWLEY, AH||GABBAI, FP||BERTRAND, G||CARRANO, CJ||BOND, MR

publication date

• May 1995

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• Bis(amino)phosphine Azide Complexes
• Reactivity
• X-ray Structure

Digital Object Identifier (DOI)

• 10.1016/0022-328X(95)91149-E

start page

• 95

end page

• 99

volume

• 493

issue

• 1-2

URL

• http://dx.doi.org/10.1016/0022-328x(95)91149-e