VIBRATIONAL SPECTRA AND FORCE CONSTANTS FOR ISOTOPIC SPECIES OF NITROSYL BROMIDE Academic Article

abstract

• From infrared absorption studies in the gaseous phase, the fundamental harmonic vibrational frequencies have been determined for 16O14NBr, 16O15NBr, 18O14NBr, and 18O15NBr. With the aid of centrifugal distortion data from the literature, a unique general quadratic valence force constant solution was obtained. The resulting values are: FNO = 15.25 md/A, FNBr = 1.13 md/A, F = 1.13 md A/rad2, FNO,NBr = 1.47 md/A, FNO, = 0.11 md/rad, and FNBr, = 0.10 md/rad. Interaction displacement coordinates were calculated and were used along with the force constants to describe the bonding in ONBr, ONCl, and ONF. 1969.

authors

• Laane, Jaan

published proceedings

• JOURNAL OF MOLECULAR SPECTROSCOPY

author list (cited authors)

• LAANE, J., JONES, L. H., RYAN, R. R., & ASPREY, L. B.

citation count

• 36

complete list of authors

• LAANE, J||JONES, LH||RYAN, RR||ASPREY, LB

publication date

• January 1969

publisher

• Elsevier  Publisher

published in

• Journal of Molecular Spectroscopy  Journal

keywords

• 34 Chemical Sciences
• 3406 Physical Chemistry
• 3407 Theoretical And Computational Chemistry

Digital Object Identifier (DOI)

• 10.1016/0022-2852(69)90280-X

start page

• 485

end page

• &

volume

• 30

issue

• 3

URL

• http://dx.doi.org/10.1016/0022-2852(69)90280-x