VIBRATIONAL SPECTRA AND NORMAL-COORDINATE ANALYSES OF SILACYCLOBUTANES Academic Article

abstract

• The complete vibrational spectra of silacyclobutane, (CH2)3SiH2, and of three of its derivatives, (CH2)3SiX3 where X = D, F, Cl, have been recorded and an assignment for each molecule is proposed. A normal-coordinate calculation for each of these molecules was carried out to test the assignment and to demonstrate coupling between various vibrational modes. Considerable mixing of the modes was found. An analysis of the spectra shows that all four of these four-membered ring compounds are non-planar and have C3 symmetry. 1970.

authors

• Laane, Jaan

published proceedings

• SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY

author list (cited authors)

• LAANE, J.

citation count

• 43

complete list of authors

• LAANE, J

publication date

• March 1970

publisher

• Elsevier  Publisher

published in

• n1386-1425ISSN  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry
• 3406 Physical Chemistry
• 3407 Theoretical And Computational Chemistry

Digital Object Identifier (DOI)

• 10.1016/0584-8539(70)80099-X

start page

• 517

end page

• &

volume

• A 26

issue

• 3

URL

• http://dx.doi.org/10.1016/0584-8539(70)80099-x