FAR INFRARED SPECTRA OF RING COMPOUNDS .6. SPECTRUM AND CONFORMATION OF 1,4-CYCLOHEXADIENE Academic Article

abstract

• The absorption spectrum of 1,4-cyclohexadiene vapor in the range 60-250 cm-1 shows only one band, which is of type C with Q-branch peaks of decreasing intensity in the order 107.7, 108.4, 107.0, 106.35, 105.75, 105.2, and 104.7 cm-1. These are assigned to the B2u ring-puckering vibration of a D2h structure having a planar ring. A potential function computed a priori from the torsional and angle-bending potentials appropriate to this vibration gives fairly good quantitative agreement with the observed frequencies. 1971.

authors

• Laane, Jaan

published proceedings

• JOURNAL OF MOLECULAR SPECTROSCOPY

author list (cited authors)

• LAANE, J., & LORD, R. C.

citation count

• 35

complete list of authors

• LAANE, J||LORD, RC

publication date

• August 1971

publisher

• Elsevier  Publisher

published in

• Journal of Molecular Spectroscopy  Journal

Digital Object Identifier (DOI)

• 10.1016/0022-2852(71)90064-6

start page

• 340

end page

• &

volume

• 39

issue

• 2

URL

• http://dx.doi.org/10.1016/0022-2852(71)90064-6