NORMAL COORDINATE ANALYSES OF DIMETHYL PEROXIDES Academic Article

abstract

• The general quadratic force field has been determined for the vibrations of CH3OOCH3 and CD3OOCD3. Twenty-one non-zero force constants were used to fit the forty-two assigned fundamental frequencies, a number of which were revised in this work. Several of the vibrational modes, especially those for the deuteride, were found to be strongly coupled. The oxygen-oxygen stretching motion, in particular, was found to be highly coupled for both molecules. Because of this, the O-O stretching frequency cannot be considered to be a reliable measure of the oxygen-oxygen bond strength. 1972.

authors

• Laane, Jaan

published proceedings

• SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY

author list (cited authors)

• BELL, M., & LAANE, J.

citation count

• 29

complete list of authors

• BELL, MEB||LAANE, J

publication date

• November 1972

publisher

• Elsevier  Publisher

published in

• n1386-1425ISSN  Journal

Digital Object Identifier (DOI)

• 10.1016/0584-8539(72)80198-3

start page

• 2239

end page

• &

volume

• A 28

issue

• 11

URL

• http://dx.doi.org/10.1016/0584-8539(72)80198-3