VIBRATIONAL ANALYSES OF SILACYCLOPENTANES Academic Article uri icon

abstract

  • The complete infrared and Raman spectra of 1,1-difluoro-1-silacyclopentane and 1,1-dichloro-1-silacyclopentane have been recorded and analyzed. Furthermore, a number of the vibrational frequencies of the silacyclopentane and silacyclopentane-1, 1-d2 molecules have been reassigned. A normal coordinate calculation for each of these molecules was carried out and this demonstrated the validity of the assignments. Considerable mixing of the modes was found especially where ring vibrations and SiX2 motions were involved. 1973.

published proceedings

  • JOURNAL OF MOLECULAR STRUCTURE

author list (cited authors)

  • PHILEN, D. L., CHAO, T. H., & LAANE, J.

citation count

  • 22

complete list of authors

  • PHILEN, DL||CHAO, TH||LAANE, J

publication date

  • June 1973