VIBRATIONAL-SPECTRA AND RING-PUCKERING OF 2-CYCLOPENTEN-1-ONES Academic Article

abstract

• The mid-infrared, far-infrared, and Raman spectra of 2-cyclopenten-1-one and 2-cyclopenten-1-one-5, 5-d2 have been recorded. Assignments for each of the thirty vibrational fundamentals have been made for the two molecules. Several ring-puckering transitions were observed in the far-infrared spectrum of each molecule. From these were determined potential functions which establish the planarity of the ring system. The potential functions in reduced form derived for the hyride and deuteride are V = 15.0(Z4 + 8.0Z2) cm-1 and V = 14.2(Z4 + 8.8Z2) cm-1, respectively. 1973.

authors

• Laane, Jaan

published proceedings

• JOURNAL OF MOLECULAR SPECTROSCOPY

author list (cited authors)

• CHAO, T. H., & LAANE, J.

citation count

• 31

complete list of authors

• CHAO, TH||LAANE, J

publication date

• November 1973

publisher

• Elsevier  Publisher

published in

• Journal of Molecular Spectroscopy  Journal

Digital Object Identifier (DOI)

• 10.1016/0022-2852(73)90191-4

start page

• 266

end page

• 276

volume

• 48

issue

• 2

URL

• http://dx.doi.org/10.1016/0022-2852(73)90191-4