Synthesis and characterization of unsaturated Manganese(I) and Rhenium(I) dicarbonyl complexes supported by an anionic PNP pincer Academic Article

abstract

• 2019 Elsevier B.V. Syntheses of Re and Mn carbonyl complexes of the diarylamido/bis(phosphine) PNP pincer ligand are reported. The saturated (PNP)Re(CO)3 and (PNP)Mn(CO)3 react cleanly with HBr in acetic acid to undergo decarbonylation with concomitant addition of HBr across the N-M bond. The resultant (PNHP)MBr(CO)2 (M = Mn or Re) complexes can be dehydrobrominated with triethylamine to yield the unsaturated (PNP)M(CO)2. (PNP)Re(CO)2 has high affinity for CO and abstracts CO from (PNP)Mn(CO)3.

authors

• Ozerov, Oleg

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• Kosanovich, A. J., Shih, W., & Ozerov, O. V.

citation count

• 7

complete list of authors

• Kosanovich, Alex J||Shih, Wei-Chun||Ozerov, Oleg V

publication date

• January 2019

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• Carbonyl Complex
• Manganese
• Phosphine
• Pincer
• Rhenium

Digital Object Identifier (DOI)

• 10.1016/j.jorganchem.2019.06.020

start page

• 1

end page

• 6

volume

• 897

URL

• http://dx.doi.org/10.1016/j.jorganchem.2019.06.020