Hypervalent Iodine Chemistry as a Platform for Aerobic Oxidation Catalysis Academic Article

abstract

• Here, we highlight the recent development of aerobic oxidation catalysis via hypervalent I(III) and I(V) intermediates. The described chemistry intercepts reactive intermediates generated during aldehyde autoxidation to accomplish the oxidation of aryl iodides. The aerobically generated hypervalent iodine intermediates are utilized to couple an array of substrate functionalization chemistry to the reduction of O2.1Introduction2Chemistry of Aerobically Generated I(III) Intermediates3Chemistry of Aerobically Generated I(V) Intermediates4Conclusions

authors

• Powers, David

published proceedings

• SYNLETT

altmetric score

• 0.5

author list (cited authors)

• Maity, A., & Powers, D. C.

citation count

• 7

complete list of authors

• Maity, Asim||Powers, David C

publication date

• February 2019

publisher

• Thieme  Publisher

published in

• Synlett: accounts and rapid communications in synthetic organic chemistry  Journal

keywords

• Aerobic Oxidation
• Hypervalent Iodine
• Organocatalysis
• Sustainable Synthesis

Digital Object Identifier (DOI)

• 10.1055/s-0037-1610338

start page

• 257

end page

• 262

volume

• 30

issue

• 3

URL

• http://dx.doi.org/10.1055/s-0037-1610338