Sophisticated Construction of Electronically Labile Materials: A Neutral, Radical-Rich, Cobalt Valence Tautomeric Triangle. Academic Article

abstract

• Herein, we report the construction of a neutral, radical-rich, cobalt valence tautomeric triangle, which consists of two types of radical groups including tetrazine-based bridges and semiquinone anions at high temperature and has traits of high intensity and density of sensing sites. The mechanism of the Valence Tautomerism process within the triangle has been illustrated as one electron transfer, preceding a two electrons transfer along with the phenomenon of spin flipping.

authors

• Zhou, Hongcai

published proceedings

• J Am Chem Soc

altmetric score

• 0.25

author list (cited authors)

• Li, B., Wang, X., Kirchon, A., Qin, J., Pang, J., Zhuang, G., & Zhou, H.

citation count

• 17

complete list of authors

• Li, Bao||Wang, Xiao-Ning||Kirchon, Angelo||Qin, Jun-Sheng||Pang, Jian-Dong||Zhuang, Gui-Lin||Zhou, Hong-Cai

publication date

• November 2018

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

PubMed Central ID

• 30347976

Digital Object Identifier (DOI)

• 10.1021/jacs.8b09062

start page

• 14581

end page

• 14585

volume

• 140

issue

• 44

URL

• http://dx.doi.org/10.1021/jacs.8b09062