n382066SE Academic Article uri icon

abstract

  • 2018 American Chemical Society. Preparation and characterization of a series of pincer-type [P2Si]Co complexes are reported, including a crystal structure of the first base-free cobalt silylene complex. The cationic silylene complex is strongly Lewis acidic and oxophilic, readily coordinating Lewis bases such as triflate and pyridine and heterolytically cleaving the O-H bonds in ethanol and water.

published proceedings

  • Organometallics

author list (cited authors)

  • Zhang, J., Foley, B. J., Bhuvanesh, N., Zhou, J., Janzen, D. E., Whited, M. T., & Ozerov, O. V.

publication date

  • January 1, 2018 11:11 AM