Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes

abstract

• 2018 American Chemical Society. Preparation and characterization of a series of pincer-type [P2Si]Co complexes are reported, including a crystal structure of the first base-free cobalt silylene complex. The cationic silylene complex is strongly Lewis acidic and oxophilic, readily coordinating Lewis bases such as triflate and pyridine and heterolytically cleaving the O-H bonds in ethanol and water.

authors

• Ozerov, Oleg

published proceedings

• ORGANOMETALLICS

altmetric score

• 2.5

author list (cited authors)

• Zhang, J., Foley, B. J., Bhuvanesh, N., Zhou, J., Janzen, D. E., Whited, M. T., & Ozerov, O. V.

citation count

• 23

complete list of authors

• Zhang, Jia||Foley, Bryan J||Bhuvanesh, Nattamai||Zhou, Jia||Janzen, Daron E||Whited, Matthew T||Ozerov, Oleg V

publication date

• November 2018

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1021/acs.organomet.8b00594

start page

• 3956

end page

• 3962

volume

• 37

issue

• 21

URL

• http://dx.doi.org/10.1021/acs.organomet.8b00594