Towards understanding of lanthanide-transition metal bonding: investigations of the first Ce-Fe bonded complex. Academic Article uri icon

abstract

  • The syntheses, structural, and magnetic characterization of three new organometallic Ce complexes stabilized by PyCp22- (PyCp22- = [2,6-(CH2C5H3)2C5H3N]2-) are reported. Complex 1 provides the first example of a crystallographically characterized unsupported Ce-Fe bond in a molecular compound. Results from IR spectroscopy and computational analyses suggest weaker Fe → Ce electron-donation than in a previously reported Dy-Fe bonded species.

published proceedings

  • Chem Commun (Camb)

author list (cited authors)

  • Burns, C. P., Yang, X., Sung, S., Wofford, J. D., Bhuvanesh, N. S., Hall, M. B., & Nippe, M

citation count

  • 21

complete list of authors

  • Burns, Corey P||Yang, Xin||Sung, Siyoung||Wofford, Joshua D||Bhuvanesh, Nattamai S||Hall, Michael B||Nippe, Michael

publication date

  • September 2018