LINEAR FREE-ENERGY RELATIONSHIPS FOR C1-OXYGENATE DECOMPOSITION ON TRANSITION-METAL SURFACES
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abstract
Linear free energy relationships for the decomposition of formate and methoxide intermediates on metal surfaces have been developed. These demonstrate that Group VIII and Group IB metals do not obey the same correlations. Implications of these observations include the potential for misinterpretation of classical Balandin " volcano" plots. 1991 J.C. Baltzer A.G. Scientific Publishing Company.