Structure and reaction of oxametallacycles derived from styrene oxide on Ag(110) Academic Article

abstract

• Styrene oxide forms a strongly bound oxametallacycle intermediate via activated adsorption on the Ag(1 1 0) surface. The oxametallacycle species derived from styrene oxide on Ag(1 1 0) fits well with the family of oxametallacycles identified previously in studies of non-allylic epoxides with unsaturated substituent groups on silver. Temperature-programmed reaction experiments demonstrate that styrene oxide ring opens at the substituted carbon, and Density Functional Theory calculations indicate that the phenyl ring of the resulting oxametallacycle is oriented nearly parallel to the Ag(1 1 0) surface. Interaction of the phenyl group with the silver surface stabilizes this intermediate relative to that derived from the mono-olefin epoxide, ethylene oxide. During temperature-programmed reaction, the oxametallacycle undergoes ring-closure to reform styrene oxide and isomerization to phenylacetaldehyde at 505 K on Ag(1 1 0). Styrene oxide-derived oxametallacycles exhibit similar ring-closure behavior on the Ag(1 1 1) surface. 2007 Elsevier B.V. All rights reserved.

authors

• Barteau, Mark

published proceedings

• SURFACE SCIENCE

author list (cited authors)

• Lukaski, A. C., Enever, M., & Barteau, M. A.

citation count

• 6

complete list of authors

• Lukaski, AC||Enever, MCN||Barteau, MA

publication date

• August 2007

publisher

• Elsevier  Publisher

published in

• Surface Science  Journal

keywords

• Density Functional Theory
• Olefin Epoxidation Catalysis
• Oxametallacycle
• Reflection Absorption Infrared Spectroscopy
• Silver
• Styrene Oxide
• Temperature-programmed Reaction

Digital Object Identifier (DOI)

• 10.1016/j.susc.2007.06.015

start page

• 3372

end page

• 3382

volume

• 601

issue

• 16

URL

• http://dx.doi.org/10.1016/j.susc.2007.06.015