Molybdenum polyoxometalates as active species for energy storage in non-aqueous media Academic Article

abstract

• 2017 Elsevier Ltd The Keggin-type polyoxometalate Li3PMo12O40 was evaluated for energy storage applications in non-aqueous media. In acetonitrile, using a static H-cell, high coulombic efficiency (90%) and stable (>500h) charge and discharge results were obtained. Different separators taking advantage of charge and size-based differentiation were compared for this system. Celgard2325, Nafion117 and aramid nanofiber-based membranes (ANF) were examined. Both Li-exchanged Nafion117 and ANF membranes enabled stable charge/discharge cycles with high coulombic efficiency for this non-aqueous polyoxometalate system. The ANF membrane, which separates based on size, permitted operation at higher current densities than the Nafion117 ion-exchange membrane.

authors

• Barteau, Mark

published proceedings

• JOURNAL OF ENERGY STORAGE

author list (cited authors)

• Chen, J., & Barteau, M. A.

citation count

• 22

complete list of authors

• Chen, Jee-Jay J||Barteau, Mark A

publication date

• October 2017

publisher

• Elsevier  Publisher

published in

• Journal of Energy Storage  Journal

keywords

• Cyclic Voltammetry
• Non-aqueous Battery
• Novel Separators
• Polyoxometalates
• Redox Flow Battery

Digital Object Identifier (DOI)

• 10.1016/j.est.2017.07.017

start page

• 255

end page

• 261

volume

• 13

URL

• http://dx.doi.org/10.1016/j.est.2017.07.017

user-defined tag

• 7 Affordable and Clean Energy