One-dimensional assemblies of dirhodium units bridged by N,N'-dicyanoquinonediimine ligands.
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Two new 1-D compounds of Rh2(O2CCF3)4 bridged by dicyano linkers were synthesized and struturally characterized. [Rh2(O2CCF3)4 (DM-DCNQI)](C6H6) (1) and [Rh2(O2CCF3)4 (DCNNQI)](C7H8) (2) (DM-DCNQI = 2,5-dimethyl-N,N-dicyanoquinone diiimine, DCNNQI = N,N-dicyanonaphthaquinone diimine) exhibit different chain motifs because of anti versus syn N - CN linkages.