Anion dependence of Ag(I) reactions with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz): isolation of the molecular propeller compound [Ag2(bptz)3][AsF6]2. Academic Article uri icon

abstract

  • The new compound [Ag(2)(bptz)(3)][AsF(6)](2), prepared from the reaction of bptz with Ag[AsF(6)] in CH(3)CN, is stable in solution as well as the solid-state and exhibits an unprecedented propeller arrangement of three bptz ligands spanning two Ag(i) ions with [AsF(6)](-) anions located in the folds of the cation.

published proceedings

  • Chem Commun (Camb)

author list (cited authors)

  • Schottel, B. L., Bacsa, J., & Dunbar, K. R.

citation count

  • 125

complete list of authors

  • Schottel, Brandi L||Bacsa, John||Dunbar, Kim R

publication date

  • November 2004