Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents.
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The homoleptic, triphenylborane adduct of the hexacyanochromate anion was structurally characterized and found to be a product in which all six cyanide ligands have undergone isomerization to nitrile groups.
author list (cited authors)
Schelter, E. J., Shatruk, M., Heintz, R. A., Galn-Mascars, J. R., & Dunbar, K. R.
complete list of authors
Schelter, Eric J||Shatruk, Mikhail||Heintz, Robert A||Galán-Mascarós, José Ramón||Dunbar, Kim R