Coarse and fine tuning of the electronic energies of triimineplatinum(II) square-planar complexes.

abstract

• [Pt(tbtrpy)X]Y complexes (tbtrpy = 4,4',4' '-tBu3-2,2';6',2' '-terpyridine) exhibit charge-transfer absorption bands that can be drastically red-shifted to long-wavelength visible absorptions with arylthiolates as X. Further extension to the near-IR (NIR) region is achieved with 7,7,8,8-tetracyanoquinodimethane (TCNQ-) as Y-, resulting in black absorbers with continuous UV-vis-NIR absorptions and opening up potential applications in energy research.

authors

• Dunbar, Kim

published proceedings

• Inorg Chem

author list (cited authors)

• Chen, W., Reinheimer, E. W., Dunbar, K. R., & Omary, M. A.

citation count

• 17

complete list of authors

• Chen, Wei-Hsuan||Reinheimer, Eric W||Dunbar, Kim R||Omary, Mohammad A

publication date

• April 2006

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• Crystallography, X-Ray
• Electrons
• Energy Transfer
• Imines
• Ligands
• Models, Molecular
• Molecular Structure
• Organoplatinum Compounds

PubMed Central ID

• 16562930

Digital Object Identifier (DOI)

• 10.1021/ic051518c

start page

• 2770

end page

• 2772

volume

• 45

issue

• 7

URL

• http://dx.doi.org/10.1021/ic051518c

user-defined tag

• 7 Affordable and Clean Energy