Conversion of a porous material based on a Mn(II)-TCNQF(4) honeycomb net to a molecular magnet upon desolvation.
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Removal of methanol molecules from the interstices of a metal-organic framework based on a 2-D hexagonal Mn(II)-TCNQF(4) net results in stronger magnetic interactions and leads to a glassy magnetically ordered state; the magnetic behavior can be reversibly cycled upon solvation-desolvation of the material.
author list (cited authors)
Lopez, N., Zhao, H., Prosvirin, A. V., Chouai, A., Shatruk, M., & Dunbar, K. R.
complete list of authors
Lopez, Nazario||Zhao, Hanhua||Prosvirin, Andrey V||Chouai, Abdellatif||Shatruk, Michael||Dunbar, Kim R