A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase.
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abstract
The slow diffusion reaction of [Ru(2)(O(2)CCF(3))(4)(THF)(2)] with TCNQ in CH(2)Cl(2)/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru(2)] rails and TCNQ rungs in a 2 : 1 ratio.