A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase.
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The slow diffusion reaction of [Ru(2)(O(2)CCF(3))(4)(THF)(2)] with TCNQ in CH(2)Cl(2)/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru(2)] rails and TCNQ rungs in a 2 : 1 ratio.
author list (cited authors)
Motokawa, N., Oyama, T., Matsunaga, S., Miyasaka, H., Sugimoto, K., Yamashita, M., Lopez, N., & Dunbar, K. R.
complete list of authors
Motokawa, Natsuko||Oyama, Tomomi||Matsunaga, Satoshi||Miyasaka, Hitoshi||Sugimoto, Kunihisa||Yamashita, Masahiro||Lopez, Nazario||Dunbar, Kim R