An electron-transfer ferromagnet with T(c) = 107 K based on a three-dimensional [Ru2]2/TCNQ system. Academic Article

abstract

• Electron-transfer makes a magnet: 2:1 assembly of [Ru2II,IIL4] paddlewheel complexes and BDTA-TCNQ yielded a new structural type of electron-transfer system with a three-dimensional network structure which exhibits a long-range ferromagnetic transition at Tc = 107 K (see depicted vs T curve and inset view of structure along the a axis). L = m-fluorobenzoate, BTDA-TCNQ = bis(1,2,5-thiadiazolo) tetracyanoquinodimethane. 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

authors

• Dunbar, Kim

published proceedings

• Angew Chem Int Ed Engl

author list (cited authors)

• Motokawa, N., Miyasaka, H., Yamashita, M., & Dunbar, K. R.

citation count

• 119

complete list of authors

• Motokawa, Natsuko||Miyasaka, Hitoshi||Yamashita, Masahiro||Dunbar, Kim R

publication date

• September 2008

publisher

• Wiley  Publisher

keywords

• Carboxylate Ligands
• Electron Transfer
• Magnetic Properties
• Quinodimethanes
• Ruthenium

Digital Object Identifier (DOI)

• 10.1002/anie.200802574

start page

• 7760

end page

• 7763

volume

• 47

issue

• 40

URL

• http://dx.doi.org/10.1002/anie.200802574