Hexacyanoosmate(III) chemistry: preparation and magnetic properties of a pentanuclear cluster and a Prussian blue analogue with Ni(II).
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abstract
The hexacyanoosmate(III) anion was used to prepare a pentanuclear cyanide bridged molecular cluster with ligand-protected Ni(II) ions as well as the corresponding Prussian blue phase from a reaction with aqueous Ni(II) ions.