After 118 years, the isolation of two common radical anion reductants as simple, stable solids. Academic Article uri icon

abstract

  • Two common radical anion reductants, potassium benzophenone ketyl (K(Ph(2)CO)) and potassium naphthalenide (K(2)(C(10)H(8))(2)(THF)), have been isolated and characterized for the first time in solvent-free form or with low solvent content, allowing their use as pure solid reactants in preparative redox chemistry in accurate stoichiometric amounts.

published proceedings

  • Chem Commun (Camb)

altmetric score

  • 3

author list (cited authors)

  • Scott, T. A., Ooro, B. A., Collins, D. J., Shatruk, M., Yakovenko, A., Dunbar, K. R., & Zhou, H.

citation count

  • 57

complete list of authors

  • Scott, Thomas A||Ooro, Betty A||Collins, David J||Shatruk, Michael||Yakovenko, Andrey||Dunbar, Kim R||Zhou, Hong-Cai

publication date

  • January 2009