A thermally and hydrolytically stable microporous framework exhibiting single-chain magnetism: structure and properties of [Co2(H0.67bdt)3] x 20 H2O. Academic Article uri icon

abstract

  • Fixing a hole: Hydrothermal chemistry has been exploited in the preparation of a 3D framework material exhibiting 48% accessible void volume and 1.5% hydrogen uptake by weight at 120 kPa (see picture). The title compound also exhibits single-chain magnetic behavior and reversible changes in magnetic properties upon solvation and desolvation.

published proceedings

  • Angew Chem Int Ed Engl

author list (cited authors)

  • Ouellette, W., Prosvirin, A. V., Whitenack, K., Dunbar, K. R., & Zubieta, J.

citation count

  • 168

complete list of authors

  • Ouellette, Wayne||Prosvirin, Andrey V||Whitenack, Kelly||Dunbar, Kim R||Zubieta, Jon

publication date

  • March 2009

publisher