An unprecedented charge transfer induced spin transition in an Fe-Os cluster. Academic Article

abstract

• ("Figure Presented") High 'n low: The novel {[Fe(tmphen) 2]3[Os(CN)6]J2} complex (see structure) is the first example of a cluster in which a highspin Fe ||| ion is in a coordination environment of four imine nitrogen atoms and two N-coordinated cyanides. Magnetic studies reveal an unprecedented type of reversible charge transfer induced spin transition (CTIST) between the low-spin Fe||-NC-Os||| and high-spin Fe |||-NC-Os||| systems. 2010 Wiley-VCH Verlag GmbH &. Co. KGaA,.

authors

• Dunbar, Kim

published proceedings

• Angew Chem Int Ed Engl

author list (cited authors)

• Hilfiger, M. G., Chen, M., Brinzari, T. V., Nocera, T. M., Shatruk, M., Petasis, D. T., ... Dunbar, K. R.

citation count

• 97

complete list of authors

• Hilfiger, Matthew G||Chen, Meimei||Brinzari, Tatiana V||Nocera, Tanya M||Shatruk, Michael||Petasis, Doros T||Musfeldt, Janice L||Achim, Catalina||Dunbar, Kim R

publication date

• February 2010

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Charge Transfer
• Cyanide Ligand
• Iron Complexes
• Spin Crossover
• Spin Transition

PubMed Central ID

• 20084656

Digital Object Identifier (DOI)

• 10.1002/anie.200906264

start page

• 1410

end page

• 1413

volume

• 49

issue

• 8

URL

• http://dx.doi.org/10.1002/anie.200906264