Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3 − Academic Article uri icon

abstract

  • The trigonal bipyramidal molecules [M(tmphen)(2)](3)[Mo(CN)(6)](2).(solvent) (M = Co, Ni; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) based on the [Mo(III)(CN)(6)](3-) unit were prepared by loss of a cyanide ligand from [Mo(III)(CN)(7)](4-) and found to exhibit ferromagnetic interactions between the M(II) and Mo(III) centers.

author list (cited authors)

  • Wang, X., Hilfiger, M. G., Prosvirin, A., & Dunbar, K. R.

citation count

  • 14

publication date

  • May 2010