Trigonal bipyramidal magnetic molecules based on [Mo(III)(CN)(6)](3-). Academic Article uri icon

abstract

  • The trigonal bipyramidal molecules [M(tmphen)(2)](3)[Mo(CN)(6)](2).(solvent) (M = Co, Ni; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) based on the [Mo(III)(CN)(6)](3-) unit were prepared by loss of a cyanide ligand from [Mo(III)(CN)(7)](4-) and found to exhibit ferromagnetic interactions between the M(II) and Mo(III) centers.

published proceedings

  • Chem Commun (Camb)

author list (cited authors)

  • Wang, X., Hilfiger, M. G., Prosvirin, A., & Dunbar, K. R.

citation count

  • 16

complete list of authors

  • Wang, Xin-Yi||Hilfiger, Matthew G||Prosvirin, Andrey||Dunbar, Kim R

publication date

  • July 2010