A docosanuclear {Mo8Mn14} cluster based on [Mo(CN)7]4-. Academic Article uri icon

abstract

  • I'll take the high road: An anionic nanosize docosanuclear {Mo 8Mn14} cluster based on the [Mo (CN)7] 4- unit was synthesized and fully characterized by X-ray and magnetic studies. This molecule (see picture; Mo red, Mn purple, C gray, N blue) is the first discrete compound based on [Mo(CN)7]4- and contains the most paramagnetic centers (22) and the largest ground state spin value (S=31) for a cyanide-bridged cluster. Figure Equotion Present. 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

published proceedings

  • Angew Chem Int Ed Engl

altmetric score

  • 3

author list (cited authors)

  • Wang, X., Prosvirin, A. V., & Dunbar, K. R.

citation count

  • 67

complete list of authors

  • Wang, Xin-Yi||Prosvirin, Andrey V||Dunbar, Kim R

publication date

  • July 2010

publisher