The -accepting arene HAT(CN)6 as a halide receptor through charge transfer: multisite anion interactions and self-assembly in solution and the solid state. Academic Article

abstract

• Sensitive molecular scaffold : The exceptional -electron-acceptor strength of HAT(CN)6 renders it an excellent colori-metric halide sensor. It engages in multisite anion interactions, namely, both charge-transfer and anion-, in solution and the solid state. The halide ions are the driving elements for the spontaneous self-assembly of the sandwich-like complexes through 2,2-charge-transfer contacts. 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

authors

• Dunbar, Kim

published proceedings

• Angew Chem Int Ed Engl

altmetric score

• 3

author list (cited authors)

• Chifotides, H. T., Schottel, B. L., & Dunbar, K. R.

citation count

• 186

complete list of authors

• Chifotides, Helen T||Schottel, Brandi L||Dunbar, Kim R

publication date

• September 2010

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Anions
• Bromides
• Chlorides
• Iodides
• Molecular Structure
• Nitriles
• Quinoxalines
• Solutions

PubMed Central ID

• 20632422

Digital Object Identifier (DOI)

• 10.1002/anie.201001755

start page

• 7202

end page

• 7207

volume

• 49

issue

• 40

URL

• http://dx.doi.org/10.1002/anie.201001755