Highly conducting coordination polymers based on infinite M(4,4'-bpy) chains flanked by regular stacks of non-integer TCNQ radicals. Academic Article uri icon

abstract

  • All coordinated: Highly conducting coordination polymers of the type [M(4,4-bpy)(1-TCNQ)2(CH 3OH)2]TCNQ (M=Mn, Zn) have been realized by using TCNQ (7,7,8,8-tetracyanoquinodimethane) as a building block (see picture). Regularly spaced stacks of TCNQ are connected to a MnII-4,4-bipyridine spine by two 1-TCNQ ligands involved in a stacked column with free TCNQ radicals. Copyright 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

published proceedings

  • Angew Chem Int Ed Engl

altmetric score

  • 1.25

author list (cited authors)

  • Ballesteros-Rivas, M., Ota, A., Reinheimer, E., Prosvirin, A., Valds-Martinez, J., & Dunbar, K. R.

citation count

  • 40

complete list of authors

  • Ballesteros-Rivas, Maria||Ota, Akira||Reinheimer, Eric||Prosvirin, Andrey||Valdés-Martinez, Jesús||Dunbar, Kim R

publication date

  • October 2011

publisher