Crystal-to-crystal transformation of magnets based on heptacyanomolybdate(III) involving dramatic changes in coordination mode and ordering temperature. Academic Article uri icon

abstract

  • Two for one: Two unusual magnets based on the [Mo(CN) 7] 4- building block with Mn II linkers have been prepared with different topological 3D networks. Conversion of one into the other is triggered by dehydration during a single-crystal to single-crystal event (see picture; Mn: dark red, Mo: pink, C: green, N: blue, O: red). 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

published proceedings

  • Angew Chem Int Ed Engl

altmetric score

  • 1.1

author list (cited authors)

  • Wang, Q., Southerland, H., Li, J., Prosvirin, A. V., Zhao, H., & Dunbar, K. R.

citation count

  • 43

complete list of authors

  • Wang, Qing-Lun||Southerland, Heather||Li, Jian-Rong||Prosvirin, Andrey V||Zhao, Hanhua||Dunbar, Kim R

publication date

  • September 2012

publisher