A neutral Fe(III) compound exhibiting a two-step spin transition and dielectric anomalies. Academic Article

abstract

• The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me)H2O () was synthesized and characterized using powder/single-crystal X-ray diffraction, Mssbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound .

authors

• Dunbar, Kim

published proceedings

• Dalton Trans

altmetric score

• 1

author list (cited authors)

• Li, Z., Dai, J., Gagnon, K. J., Cai, H., Yamamoto, T., Einaga, Y., ... Xiong, R.

citation count

• 26

complete list of authors

• Li, Zhao-Yang||Dai, Jing-Wei||Gagnon, Kevin J||Cai, Hong-Ling||Yamamoto, Takashi||Einaga, Yasuaki||Zhao, Han-Hua||Kanegawa, Shinji||Sato, Osamu||Dunbar, Kim R||Xiong, Ren-Gen

publication date

• October 2013

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Dalton Transactions  Journal

keywords

• 0306 Physical Chemistry (incl. Structural)

PubMed Central ID

• 24026666

Digital Object Identifier (DOI)

• 10.1039/c3dt51554k

start page

• 14685

end page

• 14688

volume

• 42

issue

• 41

URL

• http://dx.doi.org/10.1039/c3dt51554k