A neutral Fe(III) compound exhibiting a two-step spin transition and dielectric anomalies.
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The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me)H2O () was synthesized and characterized using powder/single-crystal X-ray diffraction, Mssbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound .
author list (cited authors)
Li, Z., Dai, J., Gagnon, K. J., Cai, H., Yamamoto, T., Einaga, Y., ... Xiong, R.
complete list of authors
Li, Zhao-Yang||Dai, Jing-Wei||Gagnon, Kevin J||Cai, Hong-Ling||Yamamoto, Takashi||Einaga, Yasuaki||Zhao, Han-Hua||Kanegawa, Shinji||Sato, Osamu||Dunbar, Kim R||Xiong, Ren-Gen