A cadmium TCNQ-based semiconductor with versatile binding modes and non-integer redox states.
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The 3-D coordination polymer with the basic formula Cd2(TCNQ)3.5(H2O)2 is the first instance of the coexistence of the bridging modes 2, 3 and 4 for TCNQ in one network. Single crystal measurements revealed the compound to be a good semiconductor with a room temperature conductivity of 5.8 10(-3) S cm(-1).
author list (cited authors)
Zhang, X., Zhang, Z., Zhao, H., Mao, J., & Dunbar, K. R.
complete list of authors
Zhang, Xuan||Zhang, Zhongyue||Zhao, Hanhua||Mao, Jiang-Gao||Dunbar, Kim R