A cadmium TCNQ-based semiconductor with versatile binding modes and non-integer redox states. Academic Article uri icon

abstract

  • The 3-D coordination polymer with the basic formula Cd2(TCNQ)3.5(H2O)2 is the first instance of the coexistence of the bridging modes 2, 3 and 4 for TCNQ in one network. Single crystal measurements revealed the compound to be a good semiconductor with a room temperature conductivity of 5.8 10(-3) S cm(-1).

published proceedings

  • Chem Commun (Camb)

author list (cited authors)

  • Zhang, X., Zhang, Z., Zhao, H., Mao, J., & Dunbar, K. R.

citation count

  • 26

complete list of authors

  • Zhang, Xuan||Zhang, Zhongyue||Zhao, Hanhua||Mao, Jiang-Gao||Dunbar, Kim R

publication date

  • February 2014