Record antiferromagnetic coupling for a 3d/4d cyanide-bridged compound. Academic Article uri icon

abstract

  • The pentanuclear compound [V(II)(tmphen)2]3[Mo(III)(CN)6]2 (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) exhibits a record antiferromagnetic exchange coupling constant of J(V-Mo) = -114 cm(-1). This is the first example of a heterobimetallic cyanide compound with such strong magnetic coupling.

published proceedings

  • J Am Chem Soc

author list (cited authors)

  • Pinkowicz, D., Southerland, H., Wang, X., & Dunbar, K. R.

citation count

  • 32

complete list of authors

  • Pinkowicz, Dawid||Southerland, Heather||Wang, Xin-Yi||Dunbar, Kim R

publication date

  • July 2014