Hierarchical organization of a robust porphyrin cage self-assembled by hydrogen bonds.
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Porphyrins appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates.
author list (cited authors)
Singh, S., Aggarwal, A., Farley, C., Hageman, B. A., Batteas, J. D., & Drain, C. M.
complete list of authors
Singh, Sunaina||Aggarwal, Amit||Farley, Christopher||Hageman, Brian A||Batteas, James D||Drain, Charles Michael