Similarity Relations and Critical Constants of Heavy Fluid Alkali Metals
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Chapman and March demonstrated from experimental data on critical constants for temperature and volume of the fluid alkali metals that TCVnc = constant, where n is about 0.3. It is pointed out here that the similarity relations given by Likalter, though restricted in their validity to the heavy fluid alkali metals, yield n = 1/3. 1994, Taylor & Francis Group, LLC. All rights reserved.