Resonance signatures in the body-frame valence photoionization of CF4. Academic Article

abstract

• We present a combined experimental and theoretical investigation of the electron dynamics and body-frame angular dependence of valence photo-single ionization of CF4 and subsequent dissociation into CF3+ and F. Ionization from a valence t2 orbital shows overlapping shape resonances close to threshold that couple to the same total symmetry, leading to striking changes in the photoelectron angular distributions when viewed in the body-frame.

authors

• Lucchese, Robert

published proceedings

• Phys Chem Chem Phys

author list (cited authors)

• Larsen, K. A., Trevisan, C. S., Lucchese, R. R., Heck, S., Iskandar, W., Champenois, E., ... Rescigno, T. N.

citation count

• 10

complete list of authors

• Larsen, KA||Trevisan, CS||Lucchese, RR||Heck, S||Iskandar, W||Champenois, E||Gatton, A||Moshammer, R||Strom, R||Severt, T||Jochim, B||Reedy, D||Weller, M||Landers, AL||Williams, JB||Ben-Itzhak, I||Dörner, R||Slaughter, D||McCurdy, CW||Weber, Th||Rescigno, TN

publication date

• August 2018

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Physical Chemistry Chemical Physics  Journal

keywords

• 0202 Atomic, Molecular, Nuclear, Particle And Plasma Physics

PubMed Central ID

• 30074041

Digital Object Identifier (DOI)

• 10.1039/c8cp03637c

start page

• 21075

end page

• 21084

volume

• 20

issue

• 32

URL

• http://dx.doi.org/10.1039/c8cp03637c