Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry. Academic Article uri icon

abstract

  • A new family of mononuclear lanthanide complexes, where the eight coordinate lanthanide ions adopt a very rare cubic coordination geometry is reported. The Dy analogue exhibits SMM behavior with a Ueff value 95.7 K under a 0.02 T applied dc field. Ab initio calculations support the observed magnetic behavior.

published proceedings

  • Chem Commun (Camb)

author list (cited authors)

  • Alexandropoulos, D. I., Schulte, K. A., Vignesh, K. R., & Dunbar, K. R.

citation count

  • 12

complete list of authors

  • Alexandropoulos, Dimitris I||Schulte, Kelsey A||Vignesh, Kuduva R||Dunbar, Kim R

publication date

  • September 2018