Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry
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A new family of mononuclear lanthanide complexes, where the eight coordinate lanthanide ions adopt a very rare cubic coordination geometry is reported. The Dy analogue exhibits SMM behavior with a Ueff value 95.7 K under a 0.02 T applied dc field. Ab initio calculations support the observed magnetic behavior.
author list (cited authors)
Alexandropoulos, D. I., Schulte, K. A., Vignesh, K. R., & Dunbar, K. R.