Porphyrin Tessellation by Design: Metal-Mediated Self-Assembly of Large Arrays and Tapes.
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abstract
Twenty-one components self-assemble to form the large (ca. 25 nm2 ), planar porphyrin arrays of type 1: four dipyridylporphyrins, four tripyridylporphyrins, one tetrapyridylporphyrin, and twelve PdCl2 units.