Alpha,omega-functionalized 2,4-dimethylpentane dyads and 2,4,6-trimethylheptane triads through asymmetric hydrogenation. Academic Article

abstract

• A match made in heaven: All the possible stereoisomers of ,-functionalized 2,4-dimethylpentane dyad and 2,4,6-tri- methylheptane triad chirons (see picture; A and B, respectively; FG = functional group, PG = protecting group) can be reached by using a combination of a chiral catalyst and substrate effects in the hydrogenation of mainly nonfunctionalized alkenes. Excellent diastereo- and enantioselectivities were achieved. (Chemical Equation Presented). 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

authors

• Burgess, Kevin

published proceedings

• Angew Chem Int Ed Engl

altmetric score

• 3

author list (cited authors)

• Zhou, J., & Burgess, K.

citation count

• 80

complete list of authors

• Zhou, Jianguang||Burgess, Kevin

publication date

• February 2007

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Asymmetric Catalysis
• Homogeneous Catalysis
• Hydrogenation
• Iridium
• Polyketides

PubMed Central ID

• 17200966

Digital Object Identifier (DOI)

• 10.1002/anie.200603635

start page

• 1129

end page

• 1131

volume

• 46

issue

• 7

URL

• http://dx.doi.org/10.1002/anie.200603635