Magnetic Properties of a Terbium-[1]Ferrocenophane Complex: Analogies between Lanthanide-Ferrocenophane and Lanthanide-Bis-phthalocyanine Complexes. Academic Article

abstract

• A rare example of an organometallic terbium single-ion magnet is reported. A Tb3+ -[1]ferrocenophane complex displays a larger barrier to magnetization reversal than its isostructural Dy3+ analogue, which is reminiscent of trends observed for lanthanide-bis-phthalocyanine complexes. Detailed abinitio calculations support the experimental observations and suggest a significantly larger ground-state stabilization for the non-Kramers ion Tb3+ in the Tb complex than for the Kramers-ion Dy3+ in the Dy complex.

authors

• Nippe, Michael

published proceedings

• Angew Chem Int Ed Engl

altmetric score

• 0.75

author list (cited authors)

• Latendresse, T. P., Vieru, V., Wilkins, B. O., Bhuvanesh, N. S., Chibotaru, L. F., & Nippe, M.

citation count

• 19

complete list of authors

• Latendresse, Trevor P||Vieru, Veacheslav||Wilkins, Branford O||Bhuvanesh, Nattamai S||Chibotaru, Liviu F||Nippe, Michael

publication date

• January 2018

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Ab Initio Calculations
• Ferrocene
• Metallocenophane
• Molecular Magnetism
• Terbium

Digital Object Identifier (DOI)

• 10.1002/anie.201804075

start page

• 8164

end page

• 8169

volume

• 57

issue

• 27