Magnetic Properties of a Terbium–Ferrocenophane Complex: Analogies between Lanthanide–Ferrocenophane and Lanthanide–Bis‐phthalocyanine Complexes
- Additional Document Info
- View All
A rare example of an organometallic terbium single-ion magnet is reported. A Tb3+ -ferrocenophane complex displays a larger barrier to magnetization reversal than its isostructural Dy3+ analogue, which is reminiscent of trends observed for lanthanide-bis-phthalocyanine complexes. Detailed ab initio calculations support the experimental observations and suggest a significantly larger ground-state stabilization for the non-Kramers ion Tb3+ in the Tb complex than for the Kramers-ion Dy3+ in the Dy complex.
author list (cited authors)
Latendresse, T. P., Vieru, V., Wilkins, B. O., Bhuvanesh, N. S., Chibotaru, L. F., & Nippe, M.