Estimating the strength of the M–H–B interaction: a kinetic approach Academic Article uri icon

abstract

  • Photolysis of BzCr(CO)3 and TpMn(CO)3 in the presence of H3B·NEt3 yields a metal-borane σ complex. Displacement of the weakly coordinated borane by P(OEt)3 proceeds by a dissociative mechanism and an Eyring analysis yields the first estimate of 20 kcal mol(-1) for the strength of this novel interaction.

altmetric score

  • 0.25

author list (cited authors)

  • Sohail, M., Moncho, S., Brothers, E. N., Darensbourg, D. J., & Bengali, A. A.

citation count

  • 5

publication date

  • January 2013