Relative cooling power enhancement by tuning magneto-structural stability in Ni-Mn-In Heusler alloys Academic Article uri icon

abstract

  • © 2018 Off-stoichiometric Ni2MnIn Heusler alloys have drawn recent attention due to their large magnetocaloric entropy change associated with the first-order magneto-structural transition. Here we present crystal structural, calorimetric and magnetic studies of three compositions. Temperature-dependent X-ray diffraction shows clear structural transition from a 6M modulated monoclinic to a L21 cubic. A significant enhancement of relative cooling power (RCP) was achieved by tuning the magnetic and structural stability through minor compositional changes, with the measured results quantitatively close to the prediction as a function of the ratio between the martensitic transition (Tm) temperature and austenite Curie temperature (TC) although the maximal magnetic induced entropy change (ΔSmax) reduction is observed in the same time. The results provided an evaluation guideline of RCPs as well as magnetic-induced entropy change in designing practical active materials.

altmetric score

  • 0.25

author list (cited authors)

  • Chen, J., Bruno, N. M., Ning, Z., Shelton, W. A., Karaman, I., Huang, Y., Li, J., & Ross, J. H.

citation count

  • 8

publication date

  • May 2018