The Azide-Nitrilimine Analogy in Aluminum Chemistry
Academic Article
Overview
Identity
Additional Document Info
Other
View All
Overview
abstract
Tetracoordinate aluminum derivatives featuring an AINNCR fragment are stable and possess a rich structural diversity, as exemplified by the nitrilimines 1 and 2, similar to that observed for the related azides. Compound 1 is the first structurally characterized six-membered AIN heterocycle in which the nitrogen and aluminum centers exhibit different coordination numbers. R=P(NiPr2)2; R'=iBu; E=N, CR.