Facile and Selective Carbonylation of Methane in Superacids Academic Article uri icon

abstract

  • The carbonylation of CH4with carbon monoxide in superacids HF/SbF5or HSO3F/SbF5leads to the exclusive and quantitative formation of the acylium ion ([CH3CO]+[SbF6]-) with the concomitant stoichiometric formation of SbF3.

published proceedings

  • Advanced Synthesis and Catalysis

author list (cited authors)

  • De Rege, P., Gladysz, J. A., & Horvth, I. T.

citation count

  • 19

complete list of authors

  • De Rege, PJF||Gladysz, JA||Horváth, IT

publication date

  • December 2002