Kinetics of trifluorovinyl ether cyclopolymerization Conference Paper uri icon

abstract

  • The Raman techniques offers a convenient method for the determination of tris(trifluorovinyloxyphenyl)ethane (TVE) kinetics. Fluoroolefin was accurately monitored in the bulk or as a thin film. The order model gave a reaction order of 2.0. Rate constants changed about olefin conversion. Analysis at various temperatures revealed activation energy of 24.6 kcal/mol which compared well with other techniques.

published proceedings

  • American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

author list (cited authors)

  • Smith, D. W., Lee, S. N., Cheatham, C. M., Laane, J., Boone, H. W., Babb, D. A., & Sammler, R. L.

complete list of authors

  • Smith, DW||Lee, SN||Cheatham, CM||Laane, J||Boone, HW||Babb, DA||Sammler, RL

publication date

  • August 1998