Kinetics of trifluorovinyl ether cyclopolymerization
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abstract
The Raman techniques offers a convenient method for the determination of tris(trifluorovinyloxyphenyl)ethane (TVE) kinetics. Fluoroolefin was accurately monitored in the bulk or as a thin film. The order model gave a reaction order of 2.0. Rate constants changed about olefin conversion. Analysis at various temperatures revealed activation energy of 24.6 kcal/mol which compared well with other techniques.